Iron-Catalyzed Polyethylene Chain Growth on Zinc: Linear [alpha]-Olefins with a Poisson DistributionThis work was supported by BP plc. Dr. Gary Audley and Dr. Jane Boyle are thanked for GPC and NMR measurements, respectively
نویسندگان
چکیده
Fifty years ago Ziegler and co-workers reported the Aufbaureaktion for alkylaluminum compounds.[1] This reaction involves a stepwise insertion of ethylene into the Al C bonds of, for example, triethylaluminum to give long-chain trialkylaluminum compounds [Eq. (1)]. Today, this chaingrowth reaction is commercially exploited for the synthesis of linear -olefins and primary alcohols from ethylene.[2]
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تاریخ انتشار 2002